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Salicylates (Aspirin)


Definition


  • An acidic drug that is rapidly metabolized to an active metabolite, salicylate; also known as acetylsalicylic acid (ASA). Included in aspirin, sodium salicylate, oil of wintergreen, methyl salicylate.
  • Normal therapeutic range (serum):
    • Analgesic/antipyretic use: <60 Ž ¼g/mL
    • Anti-inflammatory use: 150 " “300 Ž ¼g/mL

Use


  • ASA and salicylate have analgesic, antipyretic, and anti-inflammatory properties; used in the treatment of RA.
  • ASA also inhibits platelet aggregation and, therefore, prolongs bleeding time.

Interpretation


  • See discussion of salicylate poisoning in Chapter 14.

Limitations


  • Requires specific test request; not usually detected in routine screens:
    • Color test:
      • Limit of detection: 40 " “50 Ž ¼g/mL
      • Suitable for blood, serum, plasma, urine
      • Not recommended for quantitative purposes due to interferences from metabolites, AND plasma constituents
  • Immunoassay
    • Serum/plasma.
    • With a Limit of quantitation: 50 Ž ¼g/mL.
    • Not whole blood.
    • Anticoagulants (heparin, citrates, oxalates, EDTA) do not interfere.
    • Do not use sodium azide in collection tubes.
    • Hemolysis produces false-negative results.
    • Hemoglobin concentrations >100 mg/dL may interfere.
  • Confirmation
    • Sample pretreatment required
    • Gas chromatography: derivatization may be necessary
    • HPLC: preferred technique for distinguishing metabolites
    • Limit of quantitation: 50 Ž ¼g/mL
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